There are frxExportFilters() function in the frxDsgnIntf which returns a pointer of the export filters collection
You can register/unregister required export filters:
frxDsgnIntf.frxExportFilters.Register(frxXLSExport1); // You can don't call this if export filter was created in the design-time or by .Create(...) constructor
Note, UnRegister() calls a destructor of export filter's class, so you should create export filter to use it again
Also you can create export filters what he need for each user
procedure TForm1.FormClick(Sender: TObject);
begin
  frxReport1.ShowReport();
end;
procedure TForm1.frxReport1BeginDoc(Sender: TObject);
var i: integer;
    P: TPopupMenu;
begin
  P := TfrxPreviewForm(frxReport1.PreviewForm).ExportPopup;
  for i := 0 to frxExportFilters.Count - 1 do
    P.Items[i].Visible := frxExportFilters[i].Filter = frxXLSExport1;
end;
Comments
You can register/unregister required export filters:
frxDsgnIntf.frxExportFilters.Register(frxXLSExport1); // You can don't call this if export filter was created in the design-time or by .Create(...) constructor
frxDsgnIntf.frxExportFilters.UnRegister(frxXLSExport1);
Note, UnRegister() calls a destructor of export filter's class, so you should create export filter to use it again
Also you can create export filters what he need for each user